66. "Spectroscopic Probes of the MOF Nanoparticle Interphase Region"
Davenport, A.; Mezerkor, C.; Negri, H.; Kempler, P.; Hamachi, L.; Bazak, J. D.; Brozek, C. K.*
In Review 2026.
Pre-print uploaded to ChemRxiv on May 4, 2026 (DOI:10.26434/chemrxiv.15002697/v1)
65. "Particle Size Controls Phase Selectivity and Lattice Flexibility in Copper Triazolate MOF Nanoparticles"
Davenport, A.; Svensson Grape, E.; Mahady, E.;† Kadota, K.; Horike, S.; Dunning, S.; Boeschoten, A.;† Brodale, P.; Hendon, C. H.; Brozek, C. K.*
In Review 2026.
Pre-print uploaded to ChemRxiv on April 28, 2026 (DOI:10.26434/chemrxiv.15002495/v1)
64. "Aligning chemical kinetics with crystallization enables millimeter-scale single crystals of conductive MOFs"
Chen, H.; Zhao, T.; Li, W.; He, L.; Guo, J.; Yao, Z.-F.; Ma, C.; Fan, Y.; Jiang, B.; Zhang, L.; Zhang, H.-Y.; Liu, S.; Zhang, Z.; Sun, L.; Yang, L.; Brozek, C. K.; Zheng, Y.-Q.; Li, J.; Chen, T.; Sun, J.; Dou, J.-H.*
In Review 2026.
63. "Redox-Active Multi-Thianthrene Cycloparaphenylenes: Synthesis and Supramolecular Properties"
Clayton, T. D.; Spaulding, V. R.; Davenport,A. M.; Zakharov, L. N.; Brozek, C. K.; Jasti, R. *
In Review 2026.
62. "Screening-Enabled Chemiresistive Moisture Sensing with Tetrathiafulvalene-Based Electrically Conductive Metal–Organic Frameworks"
Wang, Y.; Miao, X.; Kempler, P. A.; Dou, J.-H.; Brozek, C. K.; Sun, L.*
J. Am. Chem. Soc. 2025, 147, 48158.
Pre-print uploaded to ChemRxiv on November 20, 2025 (DOI:10.26434/chemrxiv-2025-gj0k1-v2)
61. "Size-Dependent Optical Band Gaps in Metal-Organic Framework Nanoparticles"
Khaliq, F.; Beck, R.; Sevensson Grape, E.; Navidi, G.; Griffith, M.;† Marshall, C.; Li, X.; Brozek, C. K.*
J. Am. Chem. Soc. 2025, 147, 45748.
Pre-print uploaded to ChemRxiv on August 18, 2025 (DOI:10.26434/chemrxiv-2025-42x1t)
60. "Turn-On Conductivity with Proton-Coupled Electron Transport in Metal-Organic Frameworks"
Svensson Grape, E.; Brozek, C. K.*
J. Am. Chem. Soc. 2025, 147, 40981.
Pre-print uploaded to ChemRxiv on May 9, 2025 (DOI:10.26434/chemrxiv-2025-h4f9w)
59. "Crystallographic Evidence of Size-Dependent Bond Flexibility in MOF Nanocrystals"
Svensson Grape, E.; Davenport, A.; Kadota, K.; Horike, S.; Brozek, C. K.*
ACS Mater. Lett. 2025, 7, 3893.
Pre-print uploaded to ChemRxiv on July 25, 2025 (DOI:10.26434/chemrxiv-2025-4xf5x)
58. "ChemFET Anion Sensor Based on MOF Nanoparticles"
Banning, D. H.; Davenport, A. M.; Lakanen, N. M.;† Huang, J.; Brozek, C. K.*, Johnson, D. W.*
ChemSusChem 2025, 90, e202400622.
57. "Tunable Interlayer Interactions in Exfoliated 2D van der Waals Framework Fe(SCN)2(pyrazine)2"
McKenzie, J.; Pennington, D. L.; Ericson, T.; Cope, E.; Kaufman, A. J.; Cozzolino, A. F.; Johnson, D. C.; Kadota, K.*; Hendon, C. H.*; Brozek, C. K.*
Adv. Mater. 2024, 36, 2409959.
Pre-print uploaded to ChemRxiv on May 31, 2024 (DOI:10.26434/chemrxiv-2024-n5dl2)
56. "Size-Dependent Spin Crossover and Bond Flexibility in Metal-Organic Framework Nanoparticles"
Davenport, A. M.; Marshall, C. R.; Nishiguchi, T.; Kadota, K.; Andreeva, A.;† Horike, S.; Brozek, C. K.*
J. Am. Chem. Soc. 2024, 146, 23692.
Pre-print uploaded to ChemRxiv on May 17, 2024 (DOI:10.26434/chemrxiv-2024-drdpr)
55. "Solvation of Nanoscale Materials"
Mapile, A. N.; Svensson Grape, E.; Brozek, C. K.*
Chem. Mater. 2024, 36, 9075.
Pre-print uploaded to ChemRxiv on May 30, 2024 (DOI:10.26434/chemrxiv-2024-4b5rs)
54. "Electrochemical Anion Sensing Using Conductive Metal-Organic Framework Nanocrystals with Confined Pores"
Huang, J.; Heffernan, K.;† Debela, T. T.; Marshall, C. R.; Davenport, A. M.; McKenzie, J.; Shen, M.; Hou, S.; Mitchell, J. M.; Ojha, K.; Hendon, C. H.; Brozek, C. K.*
J. Am. Chem. Soc. 2024, 146, 21099.
Pre-print uploaded to ChemRxiv on September 14, 2023 (DOI:10.26434/chemrxiv-2023-1mwn2)
53. "The Surface of Colloidal Metal-Organic Framework Nanocrystals Revealed by Vibrational Sum Frequency Scattering Spectroscopy"
Mapile, A.; LeRoy, M. A.; Fabrizio, K.; Scatena, L. Brozek, C. K.*
ACS Nano 2024, 18, 13406.
Pre-print uploaded to ChemRxiv on October 13, 2023 (DOI:10.26434/chemrxiv-2023-bf7wr)
52. "The Colloidal Stability and Solubility of Metal-Organic Framework Particles"
LeRoy, M. A.; Perera, A. S.; Lamichhane, S.; Mapile, A. N.; Khaliq, F.; Kadota, K.; Zhang, X.; Ha, S.; Fisher, R.; Wu, D.; Risko, C.; Brozek, C. K.*
Chem. Mater. 2024, 36, 3673.
Pre-print uploaded to ChemRxiv on November 14, 2023 (DOI:10.26434/chemrxiv-2023-90fpz)
51. "Converting Heat to Electrical Energy Using Highly Charged Polyoxometalate Electrolytes"
Svensson Grape, E.; Huang, J.; Roychowdhury, D.; Debela, T.; Chang, H.; Jenkins, A.;† Schimpf, A.; Hendon, C. H.; Brozek, C. K.*
ACS Appl. Energy Mater. 2024, 7, 11423.
Invited contritution to "Early Career Forum 2024"
Pre-print uploaded to ChemRxiv on January 9, 2024 (DOI:10.26434/chemrxiv-2024-0x0bt)
50. "Dynamic metal-linker bonds in metal-organic frameworks"
Svensson Grape, E.; Davenport, A. M.; Brozek, C. K.*
Dalton Trans. 2024, 53, 1935.
Invited Frontier Article
Pre-print uploaded to ChemRxiv on December 28, 2023 (DOI:10.26434/chemrxiv-2023-x321t)
49. "Electrically Conductive [Fe4S4]-based Organometallic Polymers"
Kadota, K.; Chen, T.; Gormley, E.; Hendon, C. H.; Dincă, M.; Brozek, C. K.*
Chem. Sci. 2023, 14, 11410.
Pre-print uploaded to ChemRxiv on April 11, 2023 (DOI:10.26434/chemrxiv-2023-p8jvp)
48. "Gram-Scale Synthesis of MIL-125 Nanoparticles and their Solution Processability"
Fabrizio, K.; Gormley, E.; Davenport, A.; Hendon, C. H.; Brozek, C. K.*
Chem. Sci. 2023, 14, 8946.
Pre-print uploaded to ChemRxiv on October 20, 2022 (DOI:10.26434/chemrxiv-2022-knxwb)
47. "Giant Redox Entropy in the Intercalation versus Surface Chemistry of Nanocrystal Frameworks with Confined Pores"
Huang, J.; Marshall, C. R.; Ojha, K.; Shen, M.; Golledge, S.; Kadota, K.; McKenzie, J.; Fabrizio, K.; Mitchell, J. B.; Khaliq, F.; Davenport, A. M.; LeRoy, M. A.; Mapile, A. N.; Debela, T. T.; Twight, L. P.; Hendon, C. H.; Brozek. C.K.*
J. Am. Chem. Soc. 2023, 145, 6257.
Pre-print uploaded to ChemRxiv on December 6, 2022 (DOI:10.26434/chemrxiv-2022-0rvh2)
46. "Size-dependent Thermal Shifts to MOF Nanocrystal Optical Gaps Induced by Dynamic Bonding"
Fabrizio, K.; Brozek, C. K.*
Nano Lett 2023, 23, 925.
Pre-print uploaded to ChemRxiv on October 21, 2022 (DOI:10.26434/chemrxiv-2022-lf9dc)
45. "Guest-Dependent Bond Flexibility in UiO-66, a 'Stable' MOF"
Fabrizio, K.; Andreeva, S. B.;† Kadota, K.; Morris, A. J.; Brozek, C. K.*
Chem. Commun. 2023, 59, 1309.
Part of the "2022 Emerging Investigators Themed Issue"
44. "Solvent-Controlled Ion-Coupled Charge Transport in Microporous Metal Chalcogenides"
McKenzie, J.; Kempler, P. A.; Brozek, C. K.*
Chem. Sci. 2022, 13, 12747.
43. "Controlling Tautomerization in Pyridine-Fused Phosphorus-Nitrogen Heterocycles"
Nolan McNeill, J. N.; Karas, L. J.; Bard, J. P.; Fabrizio, K.; Zakharov, L. N.; MacMillan, S. N.; Brozek, C. K.; Wu, J. I.; Johnson, D. W.;* Haley, M. M.*
Chem—Eur. J. 2022, 28, e2022004.
42. "Determining Optical Band Gaps of MOFs"
Fabrizio, K.; Le, K. N.; Andreeva, S. B.†; Hendon, C. H.*; Brozek, C. K.*
ACS Mater. Lett. 2022, 4, 457.
41. "Conductivity in Open Framework Chalcogenides Tuned via Band Engineering and Redox Chemistry"
McKenzie, J.; Le, K. N.; Bardgett, D. J.; Collins, K.; Ericson, T.; Wojnar, M. E.; Chouinard, J.; Golledge, S.; Cozzolino, A. F.; Johnson, D.C.; Hendon, C. H.*; Brozek, C. K.*
Chem. Mater. 2022, 34, 1905.
40. "Size-Dependent Properties of Solution-Processable Conductive MOF Nanocrystals"
Marshall, C. R.; Dvorak, J. P.; Twight, L. P.; Chen. L.; Kadota, K.; Andreeva, A. B.†; Overland, A. E.†; Ericson, T.; Cozzolino, A. F.; Brozek, C. K.*
J. Am. Chem. Soc. 2022, 144, 5784.
Pre-print uploaded to ChemRxiv on October 21, 2022 (DOI:10.26434/chemrxiv-2021-cxxlq)
39. "Cooperativity and Metal Linker Dynamics in Spin Crossover Framework Fe(1,2,3-Triazolate)2"
Andreeva, S. B.†; Le, K. N.; Kadota, K.; Horike, S.; Hendon, C. H.*; Brozek, C. K.*
Chem. Mater. 2021, 33, 8534.
38. "Chemical transformation of H2S within the pores of MOFs: formation of polysulfides"
López-Olvera, A.; Flores, J. G.; Aguilar-Pliego, J.; Brozek, C. K.*; Gutierrez-Alejandre, A.*; Ibarra, I.*
Chem. Mater. 2021, 33, 6269.
37. "On the limit of proton-coupled electronic doping in a Ti(IV)-containing MOF"
Mancuso, J.; Fabrizio, K.; Brozek, C. K.*; Hendon, C. H.*
Chem. Sci. 2021, 12, 11779.
36. "Tunable Band-Edge Potentials and Charge Storage in Colloidal Tin-Doped Indium Oxide (ITO) Nanocrystals"
Araujo, J.; Brozek, C. K.; Liu, H.; Merkulova, A.; Li, X.; Gamelin, D.*
ACS Nano 2021, 15, 14116.
35. "What Lies Beneath a MOF Crystal Structure: New Design Principles from Unexpected Behaviors"
Allendorf, M.*; Stavila, V.; Witman, M.; Brozek, C. K.; Hendon, C. H.
J. Am. Chem. Soc. 2021, 143, 6705.
34.
"Tunable Band Gaps in MUV-10(M): A Family of Photoredox-Active MOFs with Earth-Abundant Open Metal Sites"
Fabrizio, K.; Lazarou, K. A.; Payne, L. I.†; Twight, L.; Hendon, C. H.*; Brozek, C. K.*
J. Am. Chem. Soc. 2021, 143, 12609.
Pre-print uploaded to ChemRxiv on April 15, 2021 (DOI:10.26434/chemrxiv.14417465.v2)
33. "Potentially Confusing: Potentials in Electrochemistry"
Boettcher, S. W.; Oener, S. Z.; Lonergan, M. C.; Surendranath, Y.; Ardo, S.; Brozek, C. K.; Kempler, P. A.
ACS Energy Lett. 2020, 6, 261.
32. "Post-Synthetic Modification of Ionic Liquids Using Redox and Ligand-Exchange Coordination Chemistry"
LeRoy, M. A.; Mroz, A. M.; Mancuso, J. L.; Miller, A.; Van Cleve, A.; Check, C.; Heinz, H.; Hendon, C. H.; Brozek, C. K.*
J. Mat. Chem. A 2020, 8, 22674.
Pre-print uploaded to ChemRxiv on June 22, 2020 (DOI:10.26434/chemrxiv.12512675.v1)
Part of the "2020 Emerging Investigators Themed Issue"
32. "Soft Mode Metal-Linker Dynamics in Carboxylate MOFs Evidenced by Variable-Temperature Infrared Spectroscopy"
Andreeva, S. B.;† Le, K. N.; Chen, L.; Kellman, M. E.; Hendon, C. H.*; Brozek, C. K.*
J. Am. Chem. Soc. 2020, 142, 19291.
Pre-print uploaded to ChemRxiv on September 4, 2020 (DOI:10.26434/chemrxiv.12915383.v1)
30. "Experimental Evidence for a General Model of Modulated MOF Nanoparticle Growth"
Marshall, C. R.; Timmel, E.; Staudhammer, S. A.;† Brozek, C. K.*
Chem. Sci. 2020, 11, 11539.
Pre-print uploaded to ChemRxiv on September 24, 2020 (DOI:10.26434/chemrxiv.12401708.v2)
29. "Exploration of the Solid-State Sorption Properties of Shape-persistent Macrocyclic Nanocarbons as Bulk Materials and Small Aggregates"
Schaub, T. A.; Prantl, E. A.; Kohn, J.; Bursch, M.; Marshall, C. R.; Leonhardt, E. J.; Lovell, T. C.; Zakharov, L. N.; Brozek, C. K.; Waldvogel, S. R.; Grimme, S.; Jasti, R.
J. Am. Chem. Soc. 2020, 142, 8763.
28. "Computational exploration of NO single-site disproportionation on Fe-MOF-5"
Jover, J.; Brozek, C.; Dincă, M.; Lopez, N.
Chem. Mater. 2019, 31, 8875.
27. "Precision Nanotube Mimics via Self-Assembly of Programmed Carbon Nanohoops"
Van Raden, J.; Leonhardt, E.; Zakharov, L.; Pérez-Guardiola, A.; Pérez-Jiménez, Á.; Marshall, C.; Brozek, C. K.; Sancho-García, J.-C.; Jasti, R.
J. Org. Chem. 2020, 85, 129.
26. "Size Control over Metal-Organic Framework Porous Nanocrystals"
Marshall, C. R.; Staudhammer, S. A.;† Brozek, C. K.*
Chem. Sci. 2019, 10, 9396.
abstract
| supplemental information
25. "Degenerately n-Doped Colloidal PbSe Quantum Dots: Band Assignments and Electrostatic Effects"
Araujo, J. J.; Brozek, C. K.; Kroupa, D. M.; Gamelin, D. R.
Nano Lett. 2018, 18, 3893.
abstract
| supplemental information
24. "Soluble Supercapacitors: Large and Reversible Charge Storage in Colloidal Fe-Doped ZnO Nanocrystals"
Brozek, C. K.; Zhou, D.; Liu, H.; Li, X.; Kittilstved, K. R.; Gamelin, D. R.
Nano Lett. 2018, 18, 3297.
abstract
| supplemental information
23. "Copper-Coupled Electron Transfer in Colloidal Plasmonic Copper-Sulfide Nanocrystals Probed by in Situ Spectroelectrochemistry"
Hartstein, K. H.; Brozek, C. K.; Hinterding, S. O. M.; Gamelin, D. R.
J. Am. Chem. Soc. 2018, 140, 3434.
abstract
| supplemental information
22. "A Hybrid Quantum-Classical Model of Electrostatics in Multiply Charged Quantum Dots"
Liu, H.; Brozek, C. K.; Sun, S.; Lingerfelt, D. B.; Gamelin, D. R.; Li, X.
J. Phys. Chem. C 2017, 121, 26086.
abstract
21. "Dynamic Structural Flexibility of Fe-MOF-5 Evidenced by 57Fe Mössbauer Spectroscopy"
Brozek, C. K.; Ozarowski, A.; Stoian, S. A.; Dincă, M.
Inorg. Chem. Front. 2017, 3, 782.
abstract
| supplemental information
20. "Spectroelectrochemical Measurement of Surface Electrostatic Contributions to Colloidal CdSe Nanocrystal Redox Potentials"
Carroll, G. M.; Tsui, E. Y.; Brozek, C. K.; Gamelin, D. R.
Chem. Mater. 2016, 28, 7912.
abstract
| supplemental information
19. "Potentiometric Titrations for Measuring the Capacitance of Colloidal Photodoped ZnO Nanocrystals."
Brozek, C. K.; Hartstein, K. H.; Gamelin, D. R.
J. Am. Chem. Soc. 2016, 28, 10605.
abstract
| supplemental information
18. "Potentiometric Measurements of Semiconductor Nanocrystal Redox Potentials"
Carroll, G. M.; Brozek, C. K.; Hartstein, K. H.; Tsui, E. Y.; Gamelin, D. R.
J. Am. Chem. Soc. 2016, 138, 4310.
abstract
| supplemental information
17. "Selective dimerization of ethylene to 1-butene with a porous catalyst"
Metzger, E. D.; Brozek, C. K.; Comito, R. J.; Dincă, M.
ACS Central Sci. 2016, 2, 148.
abstract
| supplemental information
16. "Thermodynamics of Solvent Interaction with the Metal-Organic Framework MOF-5"
Akimbekov, Z.; Wu, D; Brozek, C. K.; Dincă, M.; Navrotsky, A.
Phys. Chem. Chem. Phys. 2016, 18, 1158.
abstract
15. "Thermodynamic parameters of cation exchange in MOF-5 and MFU-4l"
Brozek, C. K.; Dincă, M.
Chem. Commun. 2015, 51, 11780.
abstract
| supplemental information
14. "When the Solvent Locks the Cage: Theoretical Insight into the Transmetalation of MOF-5 Lattices and its Kinetic Limitations"
Bellarosa, L.; Brozek, C. K.; Garcia-Melchior, M.; Dincă, M.; López, N.
Chem. Mater. 2015, 27, 3422.
abstract
| supplemental information
13. "NO Disproportionation at a Mononuclear Site-Isolated Fe2+ Center in Fe2+-MOF-5"
Brozek, C. K.; Miller, J. T., Stoian, S. A Dincă, M.
J. Am. Chem. Soc. 2015, 137, 7495.
abstract
| supplemental information
12. "Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogs"
Brozek, C. K.; Michaelis, V. K.; Ong, T.-C.; Bellarosa, L.; López, N.; Griffin, R. G Dincă, M.
ACS Central Sci. 2015, 1, 252.
abstract
| supplemental information
11. "High Electrical Conductivity in Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2, a Semiconducting Metal-Organic Graphene Analogue"
Sheberla, D.; Sun, L.; Blood-Forsythe, M. A.; Er, S.; Wade, C. R.; Brozek, C. K.; Aspuru- Guzik, A.; Dincă, M.
J. Am. Chem. Soc. 2014, 136, 8859.
abstract
| supplemental information
10. "Cation Exchange at the Secondary Building Units of Metal-organic Frameworks"
Brozek, C. K.; Dincă, M.
Chem. Soc. Rev. 2014, 43, 5456.
abstract
9. "Solvent-Dependent Cation Exchange in Metal-organic Frameworks"
Brozek, C. K.; Bellarosa, L.; Soejima, T.; Clark, T. V.; López, N.; Dincă, M.
Chem.—Eur. J. 2014, 20, 6871.
abstract
| supplemental information
8. "One-electron Oxidation Chemistry and Subsequent Reactivity of Diiron Imido Complexes"
Kuppuswamy, S.; Powers, T. M.; Johnson, B. M.; Brozek, C. K.; Krogman, J. P.; Bezpalko, M. W.; Berben, L. A.; Keith, J. M.; Foxman, B. M.; Thomas, C. M.
Inorg. Chem. 2014, 53, 5429.
abstract
| supplemental information
7. "Ligand Redox Non-innocence in the Stiochiometric Oxidation of Mn2(2,5-dioxidoterephthalate) (Mn-MOF-74)"
Cozzolino, A. F.; Brozek, C. K.; Palmer, R. D.; Yano, J.; Li, M.; Dincă, M.
J. Am. Chem. Soc. 2014, 136, 3334.
abstract
| supplemental information
6. "A Series of C3-Symmetric Heterobimetallic Cr/M (M = Fe, Co, and Cu) Complexes"
Kuppuswamy, S.; Bezpalko, M. W.; Powers, T. M.; Wilding, M. J. T.; Brozek, C. K.; C. K.; Foxman, B. M.; Thomas, C. M.
Chem. Sci. 2014, 5, 1617.
abstract
| supplemental information
5. "Ti3+-, V2+/3+-, Cr2+/3+-, Mn2+-, and Fe2+-Substituted MOF-5 and Redox Reactivity in Cr- and Fe-MOF-5"
Brozek, C. K.; Dincă, M.
J. Am. Chem. Soc. 2013, 135, 12886.
abstract
| supplemental information
4. "Quantification of Site-Specific Cation Exchange in Metal-Organic Frameworks Using Multi-Wavelength Anomalous X-ray Dispersion"
Brozek, C. K.; Cozzolino, A. F.; Teat, S. J.; Chen, Y.-C.; Dincă, M.
Chem. Mater. 2013, 25, 2998.
abstract
| supplemental information
3. "Metal-Metal Interactions in C3-Symmetric Diiron Imido Complexes Linked by Phosphinoamide Ligands"
Kuppuswamy, S.; Powers, T. M.; Johnson, B. M.; Bezpalko, M. W.; Brozek, C. K.; Foxman, B. M.; Berben, L. A.; Thomas, C. M.
Inorg. Chem. 2013, 52, 4802.
abstract
| supplemental information
2. "Lattice-Imposed Geometry in Metal-Organic Frameworks: Lacunary Zn4O Clusters in MOF-5 Serve as Tripodal Chelating Ligands for Ni2+"
Brozek, C. K.; Dincă, M.
Chem. Sci. 2012, 3, 2110.
abstract
| supplemental information
1. "Monomeric and Dimeric Disulfide Complexes of Nickel(II)"
Iluc, V. M.; Laskowski, C. K.; Brozek, C. K.; Harrold, N. D.; Hillhouse, G. L
Inorg. Chem. 2010, 49, 6817.
abstract
| supplemental information
